Evidence for auto-catalytic mineral dissolution from surface-specific vibrational spectroscopy

Although it is well known that silica can dissolve in water, the precise mechanism is unclear. Here, the authors employ sum frequency generation spectroscopy to probe the interfacial water structure reporting directly on the underlying dissolution mechanism, which appears to be auto-catalytic.

Bibliographic Details
Main Authors: Jan Schaefer, Ellen H. G. Backus, Mischa Bonn
Format: Article
Language:English
Published: Nature Portfolio 2018-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-018-05762-9