A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis

A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis

The title compound, [Au(C9H10NOS)(C18H15P)], features a near linear P—Au—S arrangement defined by phosphane P and thiolate S atoms with the minor distortion from the ideal [P—Au—S is 177.61 (2)°] being traced in part to the close intramolecular approach of an O atom [Au...O = 3.040 (2) Å]. The packi...

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Bibliographic Details
Main Authors: Chien Ing Yeo, Sang Loon Tan, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2016-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
gold
thiocarbamate
solvatomorphs
Hirshfeld surface analysis
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016014419

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989016014419

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