A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis
The title compound, [Au(C9H10NOS)(C18H15P)], features a near linear P—Au—S arrangement defined by phosphane P and thiolate S atoms with the minor distortion from the ideal [P—Au—S is 177.61 (2)°] being traced in part to the close intramolecular approach of an O atom [Au...O = 3.040 (2) Å]. The packi...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-10-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989016014419 |
| _version_ | 1818312899461906432 |
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| author | Chien Ing Yeo Sang Loon Tan Edward R. T. Tiekink |
| author_facet | Chien Ing Yeo Sang Loon Tan Edward R. T. Tiekink |
| author_sort | Chien Ing Yeo |
| collection | DOAJ |
| description | The title compound, [Au(C9H10NOS)(C18H15P)], features a near linear P—Au—S arrangement defined by phosphane P and thiolate S atoms with the minor distortion from the ideal [P—Au—S is 177.61 (2)°] being traced in part to the close intramolecular approach of an O atom [Au...O = 3.040 (2) Å]. The packing features supramolecular layers lying parallel to (011) sustained by a combination of C—H...π and π–π [inter-centroid distance = 3.8033 (17) Å] interactions. The molecular structure and packing are compared with those determined for a previously reported hemi-methanol solvate [Kuan et al. (2008). CrystEngComm, 10, 548–564]. Relatively minor differences are noted in the conformations of the rings in the Au-containing molecules. A Hirshfeld surface analysis confirms the similarity in the packing with the most notable differences relating to the formation of C—H...S contacts between the constituents of the solvate. |
| first_indexed | 2024-12-13T08:25:11Z |
| format | Article |
| id | doaj.art-051468150325464faa37c97d51031a36 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-13T08:25:11Z |
| publishDate | 2016-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-051468150325464faa37c97d51031a362022-12-21T23:53:54ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-10-0172101446145210.1107/S2056989016014419hb7616A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysisChien Ing Yeo0Sang Loon Tan1Edward R. T. Tiekink2Research Centre for Crystalline Materials, Faculty of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, MalaysiaResearch Centre for Crystalline Materials, Faculty of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, MalaysiaResearch Centre for Crystalline Materials, Faculty of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, MalaysiaThe title compound, [Au(C9H10NOS)(C18H15P)], features a near linear P—Au—S arrangement defined by phosphane P and thiolate S atoms with the minor distortion from the ideal [P—Au—S is 177.61 (2)°] being traced in part to the close intramolecular approach of an O atom [Au...O = 3.040 (2) Å]. The packing features supramolecular layers lying parallel to (011) sustained by a combination of C—H...π and π–π [inter-centroid distance = 3.8033 (17) Å] interactions. The molecular structure and packing are compared with those determined for a previously reported hemi-methanol solvate [Kuan et al. (2008). CrystEngComm, 10, 548–564]. Relatively minor differences are noted in the conformations of the rings in the Au-containing molecules. A Hirshfeld surface analysis confirms the similarity in the packing with the most notable differences relating to the formation of C—H...S contacts between the constituents of the solvate.http://scripts.iucr.org/cgi-bin/paper?S2056989016014419crystal structuregoldthiocarbamatesolvatomorphsHirshfeld surface analysis |
| spellingShingle | Chien Ing Yeo Sang Loon Tan Edward R. T. Tiekink A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis Acta Crystallographica Section E: Crystallographic Communications crystal structure gold thiocarbamate solvatomorphs Hirshfeld surface analysis |
| title | A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis |
| title_full | A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis |
| title_fullStr | A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis |
| title_short | A non-solvated form of [(Z)-O-methyl-N-(2-methylphenyl)thiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis |
| title_sort | non solvated form of z o methyl n 2 methylphenyl thiocarbamato κs triphenylphosphane κp gold i crystal structure and hirshfeld surface analysis |
| topic | crystal structure gold thiocarbamate solvatomorphs Hirshfeld surface analysis |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989016014419 |
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