Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(η2-BH4)2] Dichloromethane Solvate

Binuclear Copper(I) Borohydride Complex Containing Bridging Bis(diphenylphosphino) Methane Ligands: Polymorphic Structures of [(µ2-dppm)2Cu2(η2-BH4)2] Dichloromethane Solvate

Bis(diphenylphosphino)methane copper(I) tetrahydroborate was synthesized by ligands exchange in bis(triphenylphosphine) copper(I) tetrahydroborate, and characterized by XRD, FTIR, NMR spectroscopy. According to XRD the title compound has dimeric structure, [(μ2-dppm)2Cu2(η2-BH4)2], and crystallizes...

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Bibliographic Details
Main Authors: Natalia V. Belkova, Igor E. Golub, Evgenii I. Gutsul, Konstantin A. Lyssenko, Alexander S. Peregudov, Viktor D. Makhaev, Oleg A. Filippov, Lina M. Epstein, Andrea Rossin, Maurizio Peruzzini, Elena S. Shubina
Format: Article
Language:English
Published: MDPI AG 2017-10-01
Series:Crystals
Subjects:
copper(I)
diphosphine
dppm ligand
tetrahydroborate
binuclear complex
crystal structure
conformations
polymorph
hydride-halogen bonding
Online Access:https://www.mdpi.com/2073-4352/7/10/318

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https://www.mdpi.com/2073-4352/7/10/318

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