1-(((6-(Methoxycarbonyl)-5-oxononan-4-yl)oxy)carbonyl)cyclopropane-1-carboxylic Acid

1-(((6-(Methoxycarbonyl)-5-oxononan-4-yl)oxy)carbonyl)cyclopropane-1-carboxylic Acid

Here, we first report the 2′-acyloxy-1,3-dicarbonyl compound construction in a three-component oxidative reaction of alkyl ketene dimer with cyclic diacyl peroxide and trimethyl orthoformate. The discovered synthesis allows us to form 2′-functionalized 1,3-dicarbonyl compounds instead of the common...

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Bibliographic Details
Main Authors: Evgenii S. Gorlov, Diana V. Shuingalieva, Alexey I. Ilovaisky, Vera A. Vil’, Alexander O. Terent’ev
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Molbank
Subjects:
alkyl ketene dimer
peroxides
cyclic diacyl peroxide
oxidation
oxidative coupling
Online Access:https://www.mdpi.com/1422-8599/2023/2/M1651

Internet

https://www.mdpi.com/1422-8599/2023/2/M1651

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