The Paramagnetic or Spin Crossover Iron(III) Complexes Based-on Pentadentate Schiff Base Ligand: Crystal Structure, and Magnetic Property Investigation

The Paramagnetic or Spin Crossover Iron(III) Complexes Based-on Pentadentate Schiff Base Ligand: Crystal Structure, and Magnetic Property Investigation

A series of bi- or mononuclear hexacoordinate iron(III) complexes, [Fe(L)][Fe(bpb)(CN)2]·CH3OH·0.5H2O (1), [Fe(L)][Co(bpb)(CN)2]·CH3OH (2) [(Fe (L))2(4,4’-bipy)](BPh4)2 (3), [Fe(L)(py)](BPh4) (4) and [Fe(L)(dmap)](BPh4) (5) (bpb = 1,2-bis(pyridine-2-carboxamido)benzenate, L = N,N’-bis(2-hydroxybenzy...

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Bibliographic Details
Main Authors: Zhijie Xu, Shuo Meng, Tong Cao, Yu Xin, Mingjian Zhang, Xiaoyi Duan, Zhen Zhou, Daopeng Zhang
Format: Article
Language:English
Published: Slovenian Chemical Society 2022-12-01
Series:Acta Chimica Slovenica
Subjects:
cyanide-bridged
ferromagneitic coupling
spin crossover
dft calculation
Online Access:https://journals.matheo.si/index.php/ACSi/article/view/7680

Internet

https://journals.matheo.si/index.php/ACSi/article/view/7680

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