Matrix effect in analysis of pesticide residues in fruits and vegetables by high performance liquid chromatography with quadrupole-time of flight mass spectrometry

For modern food safety control are using techniques that allow to determinate a large number of components. So for determination of pesticide residues in fruits and vegetables commonly used methods of gas and liquid chromatography with time-of-flight mass-spectrometric detection. This system allows...

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Main Authors: Andoralov A.M., Kuznetsov S.V., Afonin M.B.
Format: Article
Language:deu
Published: Academician I.G. Petrovskii Bryansk State University 2017-03-01
Series:Naučno-Tehničeskij Vestnik Brânskogo Gosudarstvennogo Universiteta
Subjects:
Online Access:http://ntv-brgu.ru/wp-content/arhiv/2017-N1/2017-01-01.pdf
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author Andoralov A.M.
Kuznetsov S.V.
Afonin M.B.
author_facet Andoralov A.M.
Kuznetsov S.V.
Afonin M.B.
author_sort Andoralov A.M.
collection DOAJ
description For modern food safety control are using techniques that allow to determinate a large number of components. So for determination of pesticide residues in fruits and vegetables commonly used methods of gas and liquid chromatography with time-of-flight mass-spectrometric detection. This system allows to carry out quantitative determination several hundreds of pesticides and their identification by the characteristic fragments of the mass spectrum. The main problem when using mass spectrometric detection is a matrix effect, which is caused by the influence of matrix components extracted with pesticides from the sample. In this work, attempts have been made to reduce the influence of the matrix in the analysis of pesticide residues by high performance liquid chromatography with time of flight mass spectrometry (HPLC / TOFMS).
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spelling doaj.art-06201e036b674201872ddec34ef441eb2022-12-21T21:09:07ZdeuAcademician I.G. Petrovskii Bryansk State UniversityNaučno-Tehničeskij Vestnik Brânskogo Gosudarstvennogo Universiteta2413-99202017-03-013191710.22281/2413-9920-2017-03-01-09-17Matrix effect in analysis of pesticide residues in fruits and vegetables by high performance liquid chromatography with quadrupole-time of flight mass spectrometryAndoralov A.M.0Kuznetsov S.V.1Afonin M.B.2Vladimir State UniversityAcademician I.G. Petrovskii Bryansk State UniversityAcademician I.G. Petrovskii Bryansk State UniversityFor modern food safety control are using techniques that allow to determinate a large number of components. So for determination of pesticide residues in fruits and vegetables commonly used methods of gas and liquid chromatography with time-of-flight mass-spectrometric detection. This system allows to carry out quantitative determination several hundreds of pesticides and their identification by the characteristic fragments of the mass spectrum. The main problem when using mass spectrometric detection is a matrix effect, which is caused by the influence of matrix components extracted with pesticides from the sample. In this work, attempts have been made to reduce the influence of the matrix in the analysis of pesticide residues by high performance liquid chromatography with time of flight mass spectrometry (HPLC / TOFMS).http://ntv-brgu.ru/wp-content/arhiv/2017-N1/2017-01-01.pdfliquid chromatographymass spectrometrytime-of-flightpesticidesmatrix effectresiduesfruitsvegetables
spellingShingle Andoralov A.M.
Kuznetsov S.V.
Afonin M.B.
Matrix effect in analysis of pesticide residues in fruits and vegetables by high performance liquid chromatography with quadrupole-time of flight mass spectrometry
Naučno-Tehničeskij Vestnik Brânskogo Gosudarstvennogo Universiteta
liquid chromatography
mass spectrometry
time-of-flight
pesticides
matrix effect
residues
fruits
vegetables
title Matrix effect in analysis of pesticide residues in fruits and vegetables by high performance liquid chromatography with quadrupole-time of flight mass spectrometry
title_full Matrix effect in analysis of pesticide residues in fruits and vegetables by high performance liquid chromatography with quadrupole-time of flight mass spectrometry
title_fullStr Matrix effect in analysis of pesticide residues in fruits and vegetables by high performance liquid chromatography with quadrupole-time of flight mass spectrometry
title_full_unstemmed Matrix effect in analysis of pesticide residues in fruits and vegetables by high performance liquid chromatography with quadrupole-time of flight mass spectrometry
title_short Matrix effect in analysis of pesticide residues in fruits and vegetables by high performance liquid chromatography with quadrupole-time of flight mass spectrometry
title_sort matrix effect in analysis of pesticide residues in fruits and vegetables by high performance liquid chromatography with quadrupole time of flight mass spectrometry
topic liquid chromatography
mass spectrometry
time-of-flight
pesticides
matrix effect
residues
fruits
vegetables
url http://ntv-brgu.ru/wp-content/arhiv/2017-N1/2017-01-01.pdf
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AT kuznetsovsv matrixeffectinanalysisofpesticideresiduesinfruitsandvegetablesbyhighperformanceliquidchromatographywithquadrupoletimeofflightmassspectrometry
AT afoninmb matrixeffectinanalysisofpesticideresiduesinfruitsandvegetablesbyhighperformanceliquidchromatographywithquadrupoletimeofflightmassspectrometry