Design of CO2 hydrogenation catalysts based on phosphane/borane frustrated Lewis pairs and xanthene-derived scaffolds

Design of CO2 hydrogenation catalysts based on phosphane/borane frustrated Lewis pairs and xanthene-derived scaffolds

New naphtho[2,1,8,7-klmn]xanthene and benzo[kl]xanthene-based intramolecular phosphane–borane frustrated Lewis pairs (FLPs) were investigated in catalyzed H2 activation and CO2 hydrogenation processes. According to DFT predictions at the B3LYP-D3 level, the presence of rigid scaffolds and increased...

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Bibliographic Details
Main Authors: Maicon Delarmelina, José Walkimar de M. Carneiro, C. Richard A. Catlow, Michael Bühl
Format: Article
Language:English
Published: Elsevier 2022-02-01
Series:Catalysis Communications
Subjects:
Frustrated Lewis pair
Xanthene
CO2 hydrogenation
Formic acid
DFT
Online Access:http://www.sciencedirect.com/science/article/pii/S1566736721001084

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http://www.sciencedirect.com/science/article/pii/S1566736721001084

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