Study on the redistribution of chlolrotrimethyl and trichlolromethyl silane —Contrast of ZSM-5 series catalysts and their theoretic explanation(M1和M3的歧化反应-ZSM-5系列催化剂效果对比及其理论解释)

Study on the redistribution of chlolrotrimethyl and trichlolromethyl silane —Contrast of ZSM-5 series catalysts and their theoretic explanation(M1和M3的歧化反应-ZSM-5系列催化剂效果对比及其理论解释)

前期工作表明,AlCl3有较好的催化一甲基三氯硅烷和三甲基氯硅烷以制备二甲基二氯硅烷的活性,载体中ZSM-5分子筛效果最好.故对ZSM-5系列催化剂（包括NaAlCl4/ZSM-5、AlCl3/ZSM-5及AlCl3与NaCl机械混合的催化剂）的催化效果进行了对比研究,并用量子化学计算提出了所得结果的理论解释.结果表明,这几组催化剂中NaAlCl4/ZSM-5催化效果最好....

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Bibliographic Details
Main Authors: XUWen-yuan(徐文媛), LIUXian-liang(刘显亮), CHENLi-ping(陈丽萍), HAOWei(郝伟), HEZhong-yi(何忠义), ZHONGYun(钟昀), HULin(胡林)
Format: Article
Language:zho
Published: Zhejiang University Press 2009-01-01
Series:Zhejiang Daxue xuebao. Lixue ban
Subjects:
zsm-5
歧化
理论
催化剂
Online Access:https://doi.org/10.3785/j.issn.1008-9497.2009.01.015

Internet

https://doi.org/10.3785/j.issn.1008-9497.2009.01.015

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