Study on the redistribution of chlolrotrimethyl and trichlolromethyl silane —Contrast of ZSM-5 series catalysts and their theoretic explanation(M1和M3的歧化反应-ZSM-5系列催化剂效果对比及其理论解释)

前期工作表明,AlCl3有较好的催化一甲基三氯硅烷和三甲基氯硅烷以制备二甲基二氯硅烷的活性,载体中ZSM-5分子筛效果最好.故对ZSM-5系列催化剂(包括NaAlCl4/ZSM-5、AlCl3/ZSM-5及AlCl3与NaCl机械混合的催化剂)的催化效果进行了对比研究,并用量子化学计算提出了所得结果的理论解释.结果表明,这几组催化剂中NaAlCl4/ZSM-5催化效果最好....

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Main Authors: XUWen-yuan(徐文媛), LIUXian-liang(刘显亮), CHENLi-ping(陈丽萍), HAOWei(郝伟), HEZhong-yi(何忠义), ZHONGYun(钟昀), HULin(胡林)
Format: Article
Language:zho
Published: Zhejiang University Press 2009-01-01
Series:Zhejiang Daxue xuebao. Lixue ban
Subjects:
Online Access:https://doi.org/10.3785/j.issn.1008-9497.2009.01.015
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author XUWen-yuan(徐文媛)
LIUXian-liang(刘显亮)
CHENLi-ping(陈丽萍)
HAOWei(郝伟)
HEZhong-yi(何忠义)
ZHONGYun(钟昀)
HULin(胡林)
author_facet XUWen-yuan(徐文媛)
LIUXian-liang(刘显亮)
CHENLi-ping(陈丽萍)
HAOWei(郝伟)
HEZhong-yi(何忠义)
ZHONGYun(钟昀)
HULin(胡林)
author_sort XUWen-yuan(徐文媛)
collection DOAJ
description 前期工作表明,AlCl3有较好的催化一甲基三氯硅烷和三甲基氯硅烷以制备二甲基二氯硅烷的活性,载体中ZSM-5分子筛效果最好.故对ZSM-5系列催化剂(包括NaAlCl4/ZSM-5、AlCl3/ZSM-5及AlCl3与NaCl机械混合的催化剂)的催化效果进行了对比研究,并用量子化学计算提出了所得结果的理论解释.结果表明,这几组催化剂中NaAlCl4/ZSM-5催化效果最好.
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spelling doaj.art-08f533141d814ad980961e64e883358e2024-03-29T01:58:26ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972009-01-01361747610.3785/j.issn.1008-9497.2009.01.015Study on the redistribution of chlolrotrimethyl and trichlolromethyl silane —Contrast of ZSM-5 series catalysts and their theoretic explanation(M1和M3的歧化反应-ZSM-5系列催化剂效果对比及其理论解释)XUWen-yuan(徐文媛)0LIUXian-liang(刘显亮)1CHENLi-ping(陈丽萍)2HAOWei(郝伟)3HEZhong-yi(何忠义)4ZHONGYun(钟昀)5HULin(胡林)6 1.School of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China( 1.华东交通大学化学化工系,江西 南昌 330013) 2.Editorial Board of Journal, Jiangxi Normal University, Nanchang 330027, China( 2.江西师范大学学报编辑部,江西 南昌 330027) 1.School of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China( 1.华东交通大学化学化工系,江西 南昌 330013) 1.School of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China( 1.华东交通大学化学化工系,江西 南昌 330013) 1.School of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China( 1.华东交通大学化学化工系,江西 南昌 330013) 1.School of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China( 1.华东交通大学化学化工系,江西 南昌 330013) 1.School of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China( 1.华东交通大学化学化工系,江西 南昌 330013)前期工作表明,AlCl3有较好的催化一甲基三氯硅烷和三甲基氯硅烷以制备二甲基二氯硅烷的活性,载体中ZSM-5分子筛效果最好.故对ZSM-5系列催化剂(包括NaAlCl4/ZSM-5、AlCl3/ZSM-5及AlCl3与NaCl机械混合的催化剂)的催化效果进行了对比研究,并用量子化学计算提出了所得结果的理论解释.结果表明,这几组催化剂中NaAlCl4/ZSM-5催化效果最好.https://doi.org/10.3785/j.issn.1008-9497.2009.01.015zsm-5歧化理论催化剂
spellingShingle XUWen-yuan(徐文媛)
LIUXian-liang(刘显亮)
CHENLi-ping(陈丽萍)
HAOWei(郝伟)
HEZhong-yi(何忠义)
ZHONGYun(钟昀)
HULin(胡林)
Study on the redistribution of chlolrotrimethyl and trichlolromethyl silane —Contrast of ZSM-5 series catalysts and their theoretic explanation(M1和M3的歧化反应-ZSM-5系列催化剂效果对比及其理论解释)
Zhejiang Daxue xuebao. Lixue ban
zsm-5
歧化
理论
催化剂
title Study on the redistribution of chlolrotrimethyl and trichlolromethyl silane —Contrast of ZSM-5 series catalysts and their theoretic explanation(M1和M3的歧化反应-ZSM-5系列催化剂效果对比及其理论解释)
title_full Study on the redistribution of chlolrotrimethyl and trichlolromethyl silane —Contrast of ZSM-5 series catalysts and their theoretic explanation(M1和M3的歧化反应-ZSM-5系列催化剂效果对比及其理论解释)
title_fullStr Study on the redistribution of chlolrotrimethyl and trichlolromethyl silane —Contrast of ZSM-5 series catalysts and their theoretic explanation(M1和M3的歧化反应-ZSM-5系列催化剂效果对比及其理论解释)
title_full_unstemmed Study on the redistribution of chlolrotrimethyl and trichlolromethyl silane —Contrast of ZSM-5 series catalysts and their theoretic explanation(M1和M3的歧化反应-ZSM-5系列催化剂效果对比及其理论解释)
title_short Study on the redistribution of chlolrotrimethyl and trichlolromethyl silane —Contrast of ZSM-5 series catalysts and their theoretic explanation(M1和M3的歧化反应-ZSM-5系列催化剂效果对比及其理论解释)
title_sort study on the redistribution of chlolrotrimethyl and trichlolromethyl silane contrast of zsm 5 series catalysts and their theoretic explanation m1和m3的歧化反应 zsm 5系列催化剂效果对比及其理论解释
topic zsm-5
歧化
理论
催化剂
url https://doi.org/10.3785/j.issn.1008-9497.2009.01.015
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