Organocatalytic asymmetric allylic amination of Morita–Baylis–Hillman carbonates of isatins

Organocatalytic asymmetric allylic amination of Morita–Baylis–Hillman carbonates of isatins

The investigation of a Lewis base catalyzed asymmetric allylic amination of Morita–Baylis–Hillman carbonates derived from isatins afforded an electrophilic pathway to access multifunctional oxindoles bearing a C3-quaternary stereocenter, provided with good to excellent enantioselectivity (up to 94%...

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Detalles Bibliográficos
Main Authors: Hang Zhang, Shan-Jun Zhang, Qing-Qing Zhou, Lin Dong, Ying-Chun Chen
Formato: Artigo
Idioma:English
Publicado: Beilstein-Institut 2012-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
allylic amination
asymmetric organocatalysis
Morita–Baylis–Hillman carbonates
2-oxindoles
quaternary chiral center
Acceso en liña:https://doi.org/10.3762/bjoc.8.139

Internet

https://doi.org/10.3762/bjoc.8.139

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