Enhancing conformational flexibility of dendronized triphenylene via diethylene glycol linkers lowers transitions of helical columnar, Frank-Kasper, and quasicrystal phases

A library of triphenylene (Tp) dendronized with self-assembling dendrons via a diethylene glycol linker was synthesized and the corresponding self-organizations were analyzed. They self-organize via a crown conformation in helical columns and spherical helices that produce hexagonal columnar, Frank-...

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Bibliographic Details
Main Authors: Mohammad R. Imam, Mihai Peterca, Qi Xiao, Virgil Percec
Format: Article
Language:English
Published: Elsevier 2022-06-01
Series:Giant
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666542522000091