Molecular Structures of the Silicon Pyridine-2-(thi)olates Me<sub>3</sub>Si(pyX), Me<sub>2</sub>Si(pyX)<sub>2</sub> and Ph<sub>2</sub>Si(pyX)<sub>2</sub> (py = 2-Pyridyl, X = O, S), and Their Intra- and Intermolecular Ligand Exchange in Solution

Molecular Structures of the Silicon Pyridine-2-(thi)olates Me<sub>3</sub>Si(pyX), Me<sub>2</sub>Si(pyX)<sub>2</sub> and Ph<sub>2</sub>Si(pyX)<sub>2</sub> (py = 2-Pyridyl, X = O, S), and Their Intra- and Intermolecular Ligand Exchange in Solution

A series of pyridine-2-olates (pyO) and pyridine-2-thiolates (pyS) of silicon was studied in solid state and in solution. The crystal structures of Me<sub>3</sub>Si(pyO) (<b>1a</b>), Me<sub>3</sub>Si(pyS) (<b>1b</b>), Me<sub>2</sub>Si(pyO)&...

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Bibliographic Details
Main Authors: Anne Seidel, Mareike Weigel, Lisa Ehrlich, Robert Gericke, Erica Brendler, Jörg Wagler
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Crystals
Subjects:
chemical shift anisotropy
2-hydroxypyridine
hypercoordination
2-mercaptopyridine
organosilanes
quantum chemical calculations
Online Access:https://www.mdpi.com/2073-4352/12/8/1054

Internet

https://www.mdpi.com/2073-4352/12/8/1054

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