Dielectric friction, violation of the Stokes-Einstein-Debye relation, and non-Gaussian transport dynamics of dipolar solutes in water
The phenomenon of dielectric friction predicts slowing down of rotational and translational diffusion of a dipolar tracer in a polar medium due to retarded response of the medium polarization. This problem is studied here by numerical simulations in which the dipole moment of the tracer (solute) is...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
American Physical Society
2021-04-01
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| Series: | Physical Review Research |
| Online Access: | http://doi.org/10.1103/PhysRevResearch.3.023025 |