Enantiopure Chiral Coordination Polymers Based on Polynuclear Paddlewheel Helices and Arsenyl Tartrate

Herein, we report the preparation of chiral, one-dimensional coordination polymers based on trinuclear paddlewheel helices [M3(dpa)4]2+ (M = Co(II) and Ni(II); dpa = the anion of 2,2′-dipyridylamine). Enantiomeric resolution of a racemic mixture of [M3(dpa)4]2+ complexes was achieved by chiral recog...

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Bibliographic Details
Main Authors: Ángela Valentín-Pérez, Ahmad Naim, Elizabeth A. Hillard, Patrick Rosa, Miguel Cortijo
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Polymers
Subjects:
Online Access:http://www.mdpi.com/2073-4360/10/3/311