Flux syntheses and single-crystal structures of CsNa10M4(AsO4)9 (M = Zr, Hf)

Flux syntheses and single-crystal structures of CsNa10M4(AsO4)9 (M = Zr, Hf)

The isostructural compounds caesium decasodium tetrazirconium nonaarsenate, CsNa10Zr4(AsO4)9, and caesium decasodium tetrahafnium nonaarsenate, CsNa10Hf4(AsO4)9, arose as unexpected single-crystal products from the reactions of Na2CO3, MO2 (M = Zr, Hf) and As2O5 in a eutectic flux of NaCl and CsCl....

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Bibliographic Details
Main Author: William T. A. Harrison
Format: Article
Language:English
Published: International Union of Crystallography 2022-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
zirconium
hafnium
arsenate
ionic conduction
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989022006338

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http://scripts.iucr.org/cgi-bin/paper?S2056989022006338

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