2,3-Dihydroferroceno[3,4]pyrrolo[2,1-b]thiazol-5(8b)-ones: Synthesis, Structure and DFT Study on the Mechanism of Chemo- and Diastereoslective Annulations of (<i>S</i><sub>p</sub>)-2-Formylferrocenecarbonyl Fluoride and (<i>S</i><sub>p</sub>)-2-Formylferrocenecarboxylic Acid

2,3-Dihydroferroceno[3,4]pyrrolo[2,1-b]thiazol-5(8b)-ones: Synthesis, Structure and DFT Study on the Mechanism of Chemo- and Diastereoslective Annulations of (<i>S</i><sub>p</sub>)-2-Formylferrocenecarbonyl Fluoride and (<i>S</i><sub>p</sub>)-2-Formylferrocenecarboxylic Acid

By means of the annulation of easy-to-handle yet sufficiently reactive (<i>S</i><sub>p</sub>)-2-formylferrocenecar- bonyl fluoride with the hydrochlorides of cysteamine and the methyl esters of enentiomer cysteines conducted in dichloromethane at room temperature in the prese...

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Bibliographic Details
Main Authors: Zoltán Kovács, Antal Csámpai
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Molecules
Subjects:
ferrocene
thiazolidine
annulation
lactame
carboxyl-activation
absolute configuration
Online Access:https://www.mdpi.com/1420-3049/26/5/1420

Internet

https://www.mdpi.com/1420-3049/26/5/1420

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