Synthesis and Properties of (1<i>R</i>(<i>S</i>),5<i>R</i>(<i>S</i>),7<i>R</i>(<i>S</i>),8<i>R</i>(<i>S</i>))-1,8-Bis(hydroxymethyl)-6-azadispiro[4.1.4.2]tridecane-6-oxyl: Reduction-Resistant Spin Labels with High Spin Relaxation Times

Synthesis and Properties of (1<i>R</i>(<i>S</i>),5<i>R</i>(<i>S</i>),7<i>R</i>(<i>S</i>),8<i>R</i>(<i>S</i>))-1,8-Bis(hydroxymethyl)-6-azadispiro[4.1.4.2]tridecane-6-oxyl: Reduction-Resistant Spin Labels with High Spin Relaxation Times

Site-directed spin labeling followed by investigation using Electron Paramagnetic Resonance spectroscopy is a rapidly expanding powerful biophysical technique to study structure, local dynamics and functions of biomolecules using pulsed EPR techniques and nitroxides are the most widely used spin lab...

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Bibliographic Details
Main Authors: Yulia V. Khoroshunova, Denis A. Morozov, Danil A. Kuznetsov, Tatyana V. Rybalova, Yurii I. Glazachev, Elena G. Bagryanskaya, Igor A. Kirilyuk
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:International Journal of Molecular Sciences
Subjects:
dispiro[pyrrolidine-2,1′-cyclopentane-5,1″-cyclopentane]
6-azadispiro[4.1.4.2]tridecane
nitrones
1,3-dipolar cycloaddition
pyrrolidine nitroxides
sterically shielded nitroxides
Online Access:https://www.mdpi.com/1422-0067/24/14/11498

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https://www.mdpi.com/1422-0067/24/14/11498

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