Synthesis of fused heterocycles from 2-aryl-5-(chlorosulfonyl)-1,3-oxazole-4-carboxylates and α-aminoazoles involving the Smiles rearrangement

Synthesis of fused heterocycles from 2-aryl-5-(chlorosulfonyl)-1,3-oxazole-4-carboxylates and α-aminoazoles involving the Smiles rearrangement

Reaction of methyl 2-aryl-5-(chlorosulfonyl)-1,3-oxazole-4-carboxylates with 1H-pyrazol-5-amines and 1H-1,2,4-triazol-5-amines proceeds with the participation of endocyclic aminoazole nitrogen atoms to yield products containing a primary amino group. Being treated by sodium hydride these products un...

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Bibliographic Details
Main Authors: Maryna Kachaeva, Stepan Pilyo, Sergiy Popilnichenko, Andrii Kornienko, Eduard Rusanov, Volodymyr Prokopenko, Vladimir Zyabrev, Volodymyr S. Brovarets
Format: Article
Language:English
Published: Growing Science 2018-11-01
Series:Current Chemistry Letters
Subjects:
1
3-Oxazole-5-sulfonyl chloride
Aminoazole
Smiles rearrangement
[1
3]Oxazolo[5
4-d]pyrimidine
Online Access:http://www.growingscience.com/ccl/Vol7/ccl_2018_12.pdf

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http://www.growingscience.com/ccl/Vol7/ccl_2018_12.pdf

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