Organophotoredox-catalyzed semipinacol rearrangement via radical-polar crossover

Although electrochemical semipinacol rearrangements have been reported, a complementary photochemical route has yet to be developed. Here the authors report an organophotoredox-catalyzed semipinacol rearrangement via radical-polar crossover.

Bibliographic Details
Main Authors: Taiga Kodo, Kazunori Nagao, Hirohisa Ohmiya
Format: Article
Language:English
Published: Nature Portfolio 2022-05-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-30395-4