Unimolecular Solvolyses in Ionic Liquid: Alcohol Dual Solvent Systems
A study was undertaken of the solvolysis of pivaloyl triflate in a variety of ionic liquid:alcohol solvent mixtures. The solvolysis is a kΔ process (i.e., a process in which ionization occurs with rearrangement), and the resulting rearranged carbocation intermediate reacts with the alcohol cosolvent...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2016-01-01
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Series: | Molecules |
Subjects: | |
Online Access: | http://www.mdpi.com/1420-3049/21/1/60 |