A Malaprade cleavage, a McMurry ring closure and an intramolecular aldol contraction of maslinic acid’s ring A
A silica gel supported Malaprade cleavage of methyl maslinoate (→3) followed by a titanium-on-graphite supported McMurry coupling was established to access a 2,12-terpenoid. The microwaves supported aldol reaction of dialdehyde 3 gave ring contracted 5. While parent maslinic acid is of minor cytotox...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2022-01-01
|
| Series: | Results in Chemistry |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2211715622002661 |