Crystal structures of diaquadi-μ-hydroxido-tris[trimethyltin(IV)] diformatotrimethylstannate(IV) and di-μ-hydroxido-tris[trimethyltin(IV)] chloride monohydrate

Crystal structures of diaquadi-μ-hydroxido-tris[trimethyltin(IV)] diformatotrimethylstannate(IV) and di-μ-hydroxido-tris[trimethyltin(IV)] chloride monohydrate

The title compounds, [Sn3(CH3)9(OH)2(H2O)2][Sn(CH3)3(CHO2)2] (1) and [Sn3(CH3)9(OH)2]Cl·H2O (2), are partially condensed products of hydrolysed trimethyltin chloride. In the structures of 1 and 2, short cationic tristannatoxanes (C9H29O2Sn3) are bridged by a diformatotrimethyltin anion or a chloride...

Full description

Bibliographic Details
Main Authors: Felix Otte, Stephan G. Koller, Christopher Golz, Carsten Strohmann
Format: Article
Language:English
Published: International Union of Crystallography 2016-10-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
tin
trimethyltin hydroxide
formate
chloride
hydrolysis
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016014912

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989016014912

Similar Items