Unexpected Formation of Oxetanes during the Synthesis of Dodeco-6,7-diuloses
During the synthesis of symmetrical dodeco-6,7-diuloses that are potential candidates for inhibition of glycosidases, an unanticipated epoxide-oxetane rearrangement was observed. A bicyclic sugar consisting of a glycal moiety and an anomeric esterified furanose was oxidized under epoxidation conditi...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2020-01-01
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Series: | Molbank |
Subjects: | |
Online Access: | https://www.mdpi.com/1422-8599/2020/1/M1108 |