Unexpected Formation of Oxetanes during the Synthesis of Dodeco-6,7-diuloses

During the synthesis of symmetrical dodeco-6,7-diuloses that are potential candidates for inhibition of glycosidases, an unanticipated epoxide-oxetane rearrangement was observed. A bicyclic sugar consisting of a glycal moiety and an anomeric esterified furanose was oxidized under epoxidation conditi...

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Bibliographic Details
Main Authors: Marius Bayer, Cäcilia Maichle-Mössmer, Thomas Ziegler
Format: Article
Language:English
Published: MDPI AG 2020-01-01
Series:Molbank
Subjects:
Online Access:https://www.mdpi.com/1422-8599/2020/1/M1108