Electrochemical oxidation of allylic CH bond for α, β-unsaturated ketones without peroxide

Electrochemical oxidation of allylic CH bond for α, β-unsaturated ketones without peroxide

α,β-Unsaturated ketone is one of the important building blocks of the plenty of alkaloids, spices and pharmaceutical agents. Herein, we describe a peroxide-free electrochemical strategy to realize site-selective allylic C − H oxidation for the synthesis of α,β-unsaturated ketones. This electrochemic...

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Bibliographic Details
Main Authors: Zhong-Lin Zang, Qi Wang, Zhi-Chao Dong, Sheng-Yao Huang, Hao-Zeng Wu, Cheng-He Zhou, Gui-Xin Cai
Format: Article
Language:English
Published: Elsevier 2023-07-01
Series:Journal of Saudi Chemical Society
Subjects:
Allylic C–H oxidation
α,β-Unsaturated ketones
Electrochemistry
Peroxide-free
Sustainable chemistry
Online Access:http://www.sciencedirect.com/science/article/pii/S1319610323000777

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http://www.sciencedirect.com/science/article/pii/S1319610323000777

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