Carbocationoids, a concept for controlling highly reactive cationic species

Abstract Carbocations, which are positively charged highly electrophilic intermediates, are efficacious for the direct alkylation of low-reactive nucleophiles. The utilization of carbocations in SN1 reactions relies on the activation of their precursors in the presence of a nucleophile. However, und...

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Bibliographic Details
Main Authors: Hikaru Fujita, Daichi Shimada, Jotaro Kudo, Kazuyuki Kosha, Satoshi Kakuyama, Hiromitsu Terasaki, Munetaka Kunishima
Format: Article
Language:English
Published: Nature Portfolio 2024-03-01
Series:Communications Chemistry
Online Access:https://doi.org/10.1038/s42004-024-01139-w