The First Homoleptic Complex of Seven-Coordinated Osmium: Synthesis and Crystallographical Evidence of Pentagonal Bipyramidal Polyhedron of Heptacyanoosmate(IV)

The First Homoleptic Complex of Seven-Coordinated Osmium: Synthesis and Crystallographical Evidence of Pentagonal Bipyramidal Polyhedron of Heptacyanoosmate(IV)

The ligand exchange in (n-Bu4N)2OsIVCl6 (n-Bu4N = tetra-n-butylammonium) leads to the formation of the osmium(IV) heptacyanide, the first fully inorganic homoleptic complex of heptacoordinated osmium. The single-crystal X-ray diffraction (SC-XRD) study reveals the pentagonal bipyramidal molecular st...

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Bibliographic Details
Main Authors: Eugenia V. Peresypkina, Anatolie Gavriluta, Kira E. Vostrikova
Format: Article
Language:English
Published: MDPI AG 2016-08-01
Series:Crystals
Subjects:
osmium
heptacyanoosmate(IV)
pentagonal bipyramid polyhedron
Online Access:http://www.mdpi.com/2073-4352/6/9/102

Internet

http://www.mdpi.com/2073-4352/6/9/102

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