Jahn-Teller distortion in bis(terpyridine)nickel(III) – Elongation or compression?
DFT methods were used to evaluate the type of Jahn-Teller distortion in the low spin d7 bis(terpyridine)nickel(III) doublet. The strain of the tridentate terpyridine ligand in bis(terpyridine)nickel(III) leads to longer Ni(III)-N terminal bond lengths than the Ni(III)-N central bonds. In addition, i...
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| Format: | Article |
| Language: | English |
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Elsevier
2023-12-01
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| Series: | Results in Chemistry |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2211715623004307 |