From Rate Measurements to Mechanistic Data for Condensed Matter Reactions: A Case Study Using the Crystallization of [Zn(OH2)6][ZnCl4]

The kinetics of crystallization of the R = 3 hydrate of zinc chloride, [Zn(OH2)6][ZnCl4], is measured by time-resolved synchrotron x-ray diffraction, time-resolved neutron diffraction, and by differential scanning calorimetry. It is shown that analysis of the rate data using the classic Kolmogorov,...

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Bibliographic Details
Main Authors: Berkley G. Hillis, Bradley P. Losey, James Weng, Nezar Ghaleb, Feier Hou, James D. Martin
Format: Article
Language:English
Published: MDPI AG 2016-12-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/7/1/11