Fully Selective Synthesis of Spirocyclic-1,2-oxazine N-Oxides via Non-Catalysed Hetero Diels-Alder Reactions with the Participation of Cyanofunctionalysed Conjugated Nitroalkenes

Fully Selective Synthesis of Spirocyclic-1,2-oxazine N-Oxides via Non-Catalysed Hetero Diels-Alder Reactions with the Participation of Cyanofunctionalysed Conjugated Nitroalkenes

Hetero Diels-Alder (HDA) reactions with the participation of E-2-aryl-1-cyano-1-nitroethenes and methylenecyclopentane were evaluated on the basis of experimental as well as quantumchemical data. It was found that contrary to most known HDA reactions, title processes are realised under non-catalytic...

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Bibliographic Details
Main Authors: Przemysław Woliński, Agnieszka Kącka-Zych, Aneta Wróblewska, Ewelina Wielgus, Rafał Dolot, Radomir Jasiński
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Molecules
Subjects:
Hetero Diels-Alder reaction
nitroalkenes
heterocycles
molecular electron density theory
conceptual density functional theory
Online Access:https://www.mdpi.com/1420-3049/28/12/4586

Internet

https://www.mdpi.com/1420-3049/28/12/4586

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