A Hydrido η1-Alkynyl Diplatinum Complex Obtained from a Phosphinito Phosphanido Complex and Trimethylsilylacetylene

A Hydrido η1-Alkynyl Diplatinum Complex Obtained from a Phosphinito Phosphanido Complex and Trimethylsilylacetylene

The reaction of (trimethylsilyl)acetylene with the phosphinito phosphanido Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)](Pt-Pt) (1) results in the protonation of the Pt-Pt bond with the formation of the bridging hydride complex [(PHCy2)(Me3SiC≡C)Pt(μ-PCy2)(μ-H) Pt(PHCy2){κP-P(O)Cy2}](P...

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Bibliographic Details
Main Authors: Mario Latronico, Vito Gallo, Elena Lalinde, Santiago Ruiz, Stefano Todisco, Piero Mastrorilli
Format: Article
Language:English
Published: MDPI AG 2014-10-01
Series:Inorganics
Subjects:
acetylide complexes
phosphinito complexes
bridging hydrides
C–H activation
Online Access:http://www.mdpi.com/2304-6740/2/4/591

Internet

http://www.mdpi.com/2304-6740/2/4/591

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