Catalytic Enantioselective Synthesis of N-C Axially Chiral <i>N</i>-(2,6-Disubstituted-phenyl)sulfonamides through Chiral Pd-Catalyzed <i>N</i>-Allylation

Catalytic Enantioselective Synthesis of N-C Axially Chiral <i>N</i>-(2,6-Disubstituted-phenyl)sulfonamides through Chiral Pd-Catalyzed <i>N</i>-Allylation

Recently, catalytic enantioselective syntheses of N-C axially chiral compounds have been reported by many groups. Most N-C axially chiral compounds prepared through a catalytic asymmetric reaction possess carboxamide or nitrogen-containing aromatic heterocycle skeletons. On the other hand, although...

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Bibliographic Details
Main Authors: Sota Fukasawa, Tatsuya Toyoda, Ryohei Kasahara, Chisato Nakamura, Yuuki Kikuchi, Akiko Hori, Gary J. Richards, Osamu Kitagawa
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Molecules
Subjects:
axial chirality
atropisomers
sulfonamides
palladium
<i>N</i>-allylation
asymmetric catalyst
Online Access:https://www.mdpi.com/1420-3049/27/22/7819

Internet

https://www.mdpi.com/1420-3049/27/22/7819

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