Studies Toward Persilylation of π-Cyclopentadienyl Complexes of Fe and Ru. Molecular Structures of [Fe(C<sub>5</sub>H<sub>5</sub>){C<sub>5</sub>(SiMe<sub>2</sub>H)<sub>5</sub>}], [Fe(C<sub>5</sub>H<sub>5</sub>){C<sub>5</sub>Br<sub>3</sub>(SiMe<sub>3</sub>)<sub>2</sub>}] and [Fe(C<sub>5</sub>H<sub>5</sub>){C<sub>5</sub>Br<sub>2</sub>(SiMe<sub>3</sub>)<sub>3</sub>}]

Studies Toward Persilylation of π-Cyclopentadienyl Complexes of Fe and Ru. Molecular Structures of [Fe(C<sub>5</sub>H<sub>5</sub>){C<sub>5</sub>(SiMe<sub>2</sub>H)<sub>5</sub>}], [Fe(C<sub>5</sub>H<sub>5</sub>){C<sub>5</sub>Br<sub>3</sub>(SiMe<sub>3</sub>)<sub>2</sub>}] and [Fe(C<sub>5</sub>H<sub>5</sub>){C<sub>5</sub>Br<sub>2</sub>(SiMe<sub>3</sub>)<sub>3</sub>}]

Increasing the number of SiMe<sub>3</sub> substituents on a cyclopentadienyl ring has, in addition to a stabilizing effect of unusual coordination geometries and oxidation states, the effect of increasing the solubility in unpolar solvents and increasing the volatility. Starting from pen...

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Bibliographic Details
Main Authors: Stefanie Bernhartzeder, Tobias Blockhaus, Markus Lang, Karlheinz Sünkel
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Inorganics
Subjects:
ferrocene
ruthenocene
silylation
persilylcyclopentadienyl complexes
X-ray diffraction
Online Access:https://www.mdpi.com/2304-6740/13/2/42

Internet

https://www.mdpi.com/2304-6740/13/2/42

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