Asymmetric catalysis in aqueous media: use of metal-chiral crown ethers as efficient chiral Lewis acid catalysts in asymmetric aldol reactions

Metal-chiral crown ether complexes have been developed as efficient chiral Lewis acid catalysts for asymmetric aldol reactions of silyl enol ethers with aldehydes in aqueous media. While many excellent catalytic asymmetric reactions have been developed recently, most of them have to be carried out u...

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Bibliographic Details
Main Authors: Shu Kobayashi, Hamada Tomoaki, Nagayama Satoshi, Manabe Kei
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2001-01-01
Series:Journal of the Brazilian Chemical Society
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532001000500006