A method of mild deoxydichlorination of aldehydes catalyzed by Triphenylphosphine oxide

A method of mild deoxydichlorination of aldehydes catalyzed by Triphenylphosphine oxide

The catalytic system of triphenylphosphine oxide and phthaloyl dichloride catalysing conversion of aldehydes to 1,1-dichlorides is reported. The reaction proceeds via a P (V) catalysis manifold in which triphenylphosphine oxide turnover is achieved using phthaloyl dichloride as a consumable reagent....

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Bibliographic Details
Main Authors: D. A. Shipilovskikh, M. F. Konkova, I. P. Nikonov, M. M. Gladysheva, S. A. Shipilovskikh
Format: Article
Language:English
Published: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2022-03-01
Series:Chimica Techno Acta
Subjects:
aldehydes
lewis base catalysis
organocatalysis
triphenylphosphine oxide
nucleophilic substitution
agricultural chemistry
Online Access:https://journals.urfu.ru/index.php/chimtech/article/view/5713

Internet

https://journals.urfu.ru/index.php/chimtech/article/view/5713

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