Highly selective palladium–benzothiazole carbene-catalyzed allylation of active methylene compounds under neutral conditions

The Pd–benzothiazol-2-ylidene complex I was found to be a chemoselective catalyst for the Tsuji–Trost allylation of active methylene compounds carried out under neutral conditions and using carbonates as allylating agents. The proposed protocol consists in a simplified procedure adopting an in situ...

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Bibliographic Details
Main Authors: Antonio Monopoli, Pietro Cotugno, Carlo G. Zambonin, Francesco Ciminale, Angelo Nacci
Format: Article
Language:English
Published: Beilstein-Institut 2015-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.11.111