A 3D Coordination Polymer Based on <i>Syn-Anti</i> Bridged [Mn(RCOO)<sub>2</sub>]<sub>n</sub> Chains Showing Spin-Canting with High Coercivity and an Ordering Temperature of 14 K

A 3D Coordination Polymer Based on <i>Syn-Anti</i> Bridged [Mn(RCOO)<sub>2</sub>]<sub>n</sub> Chains Showing Spin-Canting with High Coercivity and an Ordering Temperature of 14 K

A new 3D manganese(II) coordination polymer, formulated as [Mn<sub>3</sub>(HL)<sub>6</sub>] (<b>1</b>) (where H<sub>2</sub>L = 6-hydroxypicolinic acid), has been hydrothermally synthesized and characterized by single-crystal X-ray crystallographic anal...

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Bibliographic Details
Main Authors: Soumen Kumar Dubey, Maxcimilan Patra, Kajal Gupta, Subham Bhattacharjee, Rajat Saha, Carlos J. Gómez-García
Format: Article
Language:English
Published: MDPI AG 2023-02-01
Series:Magnetochemistry
Subjects:
3D coordination polymer
manganese(II)
6-hydroxypicolinic acid
keto-enol tautomerism
<i>syn-anti</i> carboxylate
spin-canting
Online Access:https://www.mdpi.com/2312-7481/9/2/55

Internet

https://www.mdpi.com/2312-7481/9/2/55

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