Synthesis, Structure, and Magnetic Properties of Linear Trinuclear Cu<sup>II</sup> and Ni<sup>II</sup> Complexes of Porphyrin Analogues Embedded with Binaphthol Units

Synthesis, Structure, and Magnetic Properties of Linear Trinuclear Cu<sup>II</sup> and Ni<sup>II</sup> Complexes of Porphyrin Analogues Embedded with Binaphthol Units

A porphyrin analogue embedded with (<i>S</i>)-1,1′-bi-2-naphthol units was synthesized without reducing optical purity of the original binaphthol unit. This new macrocyclic ligand provides the hexaanionic N<sub>4</sub>O<sub>4</sub> coordination environment that en...

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Bibliographic Details
Main Authors: Jun-ichiro Setsune, Shintaro Omae, Yukinori Tsujimura, Tomoyuki Mochida, Takahiro Sakurai, Hitoshi Ohta
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Symmetry
Subjects:
porphyrinoids
multinuclear complexes
chiral ligands
circular dichroism
paramagnetic NMR
magnetochemistry
Online Access:https://www.mdpi.com/2073-8994/12/10/1610

Internet

https://www.mdpi.com/2073-8994/12/10/1610

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