Ligand−Structure Effects on <i>N</i>−Heterocyclic Carbene Rhenium Photo− and Electrocatalysts of CO<sub>2</sub> Reduction

Ligand−Structure Effects on <i>N</i>−Heterocyclic Carbene Rhenium Photo− and Electrocatalysts of CO<sub>2</sub> Reduction

Three novel rhenium <i>N</i>−heterocyclic carbene complexes, [Re]−NHC−1−3 ([Re] = <i>fac</i>−Re(CO)<sub>3</sub>Br), were synthesized and characterized using a range of spectroscopic techniques. Photophysical, electrochemical and spectroelectrochemical studies were...

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Bibliographic Details
Main Authors: Lauren Kearney, Michael P. Brandon, Andrew Coleman, Ann M. Chippindale, František Hartl, Ralte Lalrempuia, Martin Pižl, Mary T. Pryce
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Molecules
Subjects:
photocatalysis
electrocatalysis
CO<sub>2</sub> reduction
rhenium
<i>N</i>−heterocyclic carbene
Online Access:https://www.mdpi.com/1420-3049/28/10/4149

Internet

https://www.mdpi.com/1420-3049/28/10/4149

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