Entropy Driven Phase Transition in Polymer Gels: Mean Field Theory

We present a mean field model of a gel consisting of P polymers, each of length L and Nz polyfunctional monomers. Each polyfunctional monomer forms z covalent bonds with the 2P bifunctional monomers at the ends of the linear polymers. We find that the entropy dependence on the number of polyfunction...

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Bibliographic Details
Main Author: Miron Kaufman
Format: Article
Language:English
Published: MDPI AG 2018-06-01
Series:Entropy
Subjects:
Online Access:http://www.mdpi.com/1099-4300/20/7/501