Polyethylene glycol-functionalized N,P-ligands enhance catalytic properties of cobalt complexes for the hydrosilylation reaction

A sequence of polyethylene glycol phosphine ligands with N donor were synthesized and coordinated with Co(BF4)2 to catalyze the hydrosilylation of olefins and silanes. When the amount of catalyst is 0.5 mol% and the temperature is 90 °C, the reaction time is 5 h, the catalytic effect is the best. Th...

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Bibliographic Details
Main Authors: Yan Yan, Jiayun Li, Ying Bai, Jiajian Peng
Format: Article
Language:English
Published: Elsevier 2023-06-01
Series:Arabian Journal of Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1878535223002058