Isolation and characterization of bis(silylene)-stabilized antimony(I) and bismuth(I) cations

Abstract Monovalent group 15 cations L2Pn + (L = σ-donor ligands, Pn = N, P, As, Sb, Bi) have attracted significant experimental and theoretical interest because of their unusual electronic structures and growing synthetic potential. Herein, we describe the synthesis of a family of antimony(I) and b...

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Bibliographic Details
Main Authors: Xuyang Wang, Binglin Lei, Zhaoyin Zhang, Ming Chen, Hua Rong, Haibin Song, Lili Zhao, Zhenbo Mo
Format: Article
Language:English
Published: Nature Portfolio 2023-05-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-023-38606-2