Mechanistic insights to drive catalytic hydrogenation of formamide intermediates to methanol via deaminative hydrogenation

Amine-promoted hydrogenation of CO2 to methanol typically proceeds via a formamide intermediate when amines are used as additives or if the hydrogenation is performed in carbon capture solvents. The catalysts used for the hydrogenation of the formamide intermediate dictate the selectivity of the pro...

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Bibliographic Details
Main Authors: Jotheeswari Kothandaraman, David J. Heldebrant, Johnny Saavedra Lopez, Robert A. Dagle
Format: Article
Language:English
Published: Frontiers Media S.A. 2023-09-01
Series:Frontiers in Energy Research
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fenrg.2023.1158499/full