Probing the magnetic superexchange couplings between terminal CuII ions in heterotrinuclear bis(oxamidato) type complexes

Probing the magnetic superexchange couplings between terminal CuII ions in heterotrinuclear bis(oxamidato) type complexes

The reaction of one equivalent of [n-Bu4N]2[Ni(opboR2)] with two equivalents of [Cu(pmdta)(X)2] afforded the heterotrinuclear CuIINiIICuII containing bis(oxamidato) type complexes [Cu2Ni(opboR2)(pmdta)2]X2 (R = Me, X = NO3– (1); R = Et, X = ClO4– (2); R = n-Pr, X = NO3– (3); opboR2 = o-phenylenebis(...

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Bibliographic Details
Main Authors: Mohammad A. Abdulmalic, Saddam Weheabby, Francois E. Meva, Azar Aliabadi, Vladislav Kataev, Bernd Büchner, Frederik Schleife, Berthold Kersting, Tobias Rüffer
Format: Article
Language:English
Published: Beilstein-Institut 2017-04-01
Series:Beilstein Journal of Nanotechnology
Subjects:
bis(oxamidato)
crystallographic characterization
diamagnetic
heteronuclear complexes
magnetic superexchange coupling
molecular structure
Online Access:https://doi.org/10.3762/bjnano.8.82

Internet

https://doi.org/10.3762/bjnano.8.82

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