Micellar effects and analytical applications of nitro substitution in 4-Nitro-N-alkyl-1,8-naphthalimide by cysteine derivatives

Micellar effects and analytical applications of nitro substitution in 4-Nitro-N-alkyl-1,8-naphthalimide by cysteine derivatives

The aromatic nucleophilic substitution reactions of the nitro group of 4-Nitro-N-alkyl-1,8-naphthalimides by thiolate anions produce fluorescent derivatives and their rates are strongly accelerated by micelles of hexadecyltrimethylammonium chloride even at low pH. Acceleration factors of this reacti...

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Bibliographic Details
Main Authors: V.S. Martins, E.R. Triboni, J.B.S. Bonilha, L.M. Gonçalves, L. Mortara, L.A.C. Carvalho, B.R. Manda, C.D. Lacerda, F.C. Meotti, M.J. Politi, H. Chaimovich, I.M. Cuccovia
Format: Article
Language:English
Published: Elsevier 2020-09-01
Series:Heliyon
Subjects:
Analytical chemistry
Organic chemistry
Thiol levels
Micellar solutions
Fluorescence assay
Protein thiols
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844020317813

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http://www.sciencedirect.com/science/article/pii/S2405844020317813

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