Optically Pure Calixarenyl Phosphine via Stereospecific Alkylation on Evans’ Oxazolidinone Moiety

A convenient protocol for the synthesis of 25,26,27-tribenzoyl-28-[((<i>S</i>)-1-diphenylphos- phanyl-propan-2-yl)oxy]-calix[4]arene via stereospecific methylation on Evans’ oxazolidinone moiety was reported. According to the <sup>13</sup>C NMR analysis of this phosphine, the...

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Bibliographic Details
Main Authors: Claude Bauder, David Sémeril
Format: Article
Language:English
Published: MDPI AG 2024-03-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/29/5/1156