Synthesis and crystal structure of diisothiocyanatotetrakis(4-methylpyridine N-oxide)cobalt(II) and diisothiocyanatotris(4-methylpyridine N-oxide)cobalt(II) showing two different metal coordination polyhedra

Synthesis and crystal structure of diisothiocyanatotetrakis(4-methylpyridine N-oxide)cobalt(II) and diisothiocyanatotris(4-methylpyridine N-oxide)cobalt(II) showing two different metal coordination polyhedra

The reaction of Co(NCS)2 with 4-methylpyridine N-oxide (C6H7NO) leads to the formation of two compounds, namely, tetrakis(4-methylpyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II), [Co(NCS)2(C6H7NO)4] (1), and tris(4-methylpyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II), [Co(NCS)2(C6H7NO)3] (2). T...

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Bibliographic Details
Main Authors: Christian Näther, Inke Jess
Format: Article
Language:English
Published: International Union of Crystallography 2024-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
synthesis
coordination compound
cobalt thiocyanate
4-methylpyridine n-oxide
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989024000471

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http://scripts.iucr.org/cgi-bin/paper?S2056989024000471

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