Photoredox/HAT dual-catalyzed carboxylation of benzyl chlorides with CO2 using thiophenolate and formate as reductants
Carboxylation of benzyl chlorides with CO2 has been developed with photoredox/HAT dual-catalysis. The reaction could be conducted at room temperature with blue LED light source. Potassium formate (HCO2K) is used as a green reductant and a catalytic amount of sodium thiophenolate (PhSNa) is applied a...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2023-12-01
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| Series: | Tetrahedron Green Chem |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2773223123000274 |