Unexpected formation of polymeric silver(I) complexes of azine-type ligand via self-assembly of Ag-salts with isatin oxamohydrazide

Isatin oxamohydrazide (L) reacted with the aqueous solution of silver nitrate at room temperature afforded the polymeric silver(I) nitrato complex, [Ag2L′(NO3)2]n, (1) of the azine ligand (L′). Similarly, the reaction of L with silver(I) perchlorate gave the [Ag2L′2(ClO4)2]n, (2) coordination polyme...

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Bibliographic Details
Main Authors: Saied M. Soliman, Jörg H. Albering, Assem Barakat
Format: Article
Language:English
Published: The Royal Society 2018-01-01
Series:Royal Society Open Science
Subjects:
Online Access:https://royalsocietypublishing.org/doi/pdf/10.1098/rsos.180434