Contact angle analysis and intermetallic compounds formation between solders and substrates under formic acid atmosphere

In 3D packaging, an increase in the solder bump density and reductions in solder-bump height are the roadblocks to using gel or liquid fluxes for the soldering process. Fluxless soldering has become a popular technology, and the formic acid (FA) atmosphere soldering is one of the most promising flux...

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Main Authors: Siliang He, Yuhao Bi, Yu-An Shen, Zhikuan Chen, Gao Yue, Chuan Hu, Hiroshi Nishikawa
Format: Article
Language:English
Published: Elsevier 2022-11-01
Series:Journal of Advanced Joining Processes
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666330922000243
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author Siliang He
Yuhao Bi
Yu-An Shen
Zhikuan Chen
Gao Yue
Chuan Hu
Hiroshi Nishikawa
author_facet Siliang He
Yuhao Bi
Yu-An Shen
Zhikuan Chen
Gao Yue
Chuan Hu
Hiroshi Nishikawa
author_sort Siliang He
collection DOAJ
description In 3D packaging, an increase in the solder bump density and reductions in solder-bump height are the roadblocks to using gel or liquid fluxes for the soldering process. Fluxless soldering has become a popular technology, and the formic acid (FA) atmosphere soldering is one of the most promising fluxless soldering techniques. In this study, the effects of FA atmosphere on contact angle and the intermetallic compounds formation between three different solders (Sn-58Bi, Sn-3.0Ag-0.5Cu, and Sn-0.5Sb) and two different substrates (Cu and Ni/Cu) were investigated. The results indicate that the wettability of those soldering systems of FA soldering is very similar to that of soldering with the solder flux. Moreover, the effect of pre-heat treatment on the wettability of the Sn-3.0Ag-0.5Cu solder (SAC)/Cu by FA soldering was investigated. With the increase in the pre-heat time, the soldering wettability was improved. And there was no significant difference in the interfacial reactions of SAC/Cu between FA and flux soldering according to the microstructural study results before and thermal aging. This paper verifies that the FA atmosphere is suitable for various lead-free solders and substrates to achieve fluxless soldering and then provides a theoretical reference for the industrialization of formic acid atmosphere in electronic packaging.
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spelling doaj.art-1c5f3da602874a2191c3d46e4a6c268e2022-12-22T04:19:53ZengElsevierJournal of Advanced Joining Processes2666-33092022-11-016100118Contact angle analysis and intermetallic compounds formation between solders and substrates under formic acid atmosphereSiliang He0Yuhao Bi1Yu-An Shen2Zhikuan Chen3Gao Yue4Chuan Hu5Hiroshi Nishikawa6Institute of Semiconductors, Guangdong Academy of Sciences, Guangzhou, Guangdong 510650, China; Guangxi Key Laboratory of Manufacturing System & Advanced Manufacturing Technology, School of Mechanical and Electrical Engineering, Guilin University of Electronic Technology, Guilin, Guangxi 541004, China; Joining and Welding Research Institute, Osaka University, Osaka Ibaraki 565-0047, Japan; Corresponding authors at: Institute of Semiconductors, Guangdong Academy of Sciences, Guangzhou, Guangdong 510650, China.Institute of Semiconductors, Guangdong Academy of Sciences, Guangzhou, Guangdong 510650, China; Guangxi Key Laboratory of Manufacturing System & Advanced Manufacturing Technology, School of Mechanical and Electrical Engineering, Guilin University of Electronic Technology, Guilin, Guangxi 541004, ChinaDepartment of Materials Science and Engineering, Feng Chia University, Taichung 407, TaiwanInstitute of Semiconductors, Guangdong Academy of Sciences, Guangzhou, Guangdong 510650, ChinaGuangxi Key Laboratory of Manufacturing System & Advanced Manufacturing Technology, School of Mechanical and Electrical Engineering, Guilin University of Electronic Technology, Guilin, Guangxi 541004, China; Corresponding authors at: Institute of Semiconductors, Guangdong Academy of Sciences, Guangzhou, Guangdong 510650, China.Institute of Semiconductors, Guangdong Academy of Sciences, Guangzhou, Guangdong 510650, ChinaJoining and Welding Research Institute, Osaka University, Osaka Ibaraki 565-0047, JapanIn 3D packaging, an increase in the solder bump density and reductions in solder-bump height are the roadblocks to using gel or liquid fluxes for the soldering process. Fluxless soldering has become a popular technology, and the formic acid (FA) atmosphere soldering is one of the most promising fluxless soldering techniques. In this study, the effects of FA atmosphere on contact angle and the intermetallic compounds formation between three different solders (Sn-58Bi, Sn-3.0Ag-0.5Cu, and Sn-0.5Sb) and two different substrates (Cu and Ni/Cu) were investigated. The results indicate that the wettability of those soldering systems of FA soldering is very similar to that of soldering with the solder flux. Moreover, the effect of pre-heat treatment on the wettability of the Sn-3.0Ag-0.5Cu solder (SAC)/Cu by FA soldering was investigated. With the increase in the pre-heat time, the soldering wettability was improved. And there was no significant difference in the interfacial reactions of SAC/Cu between FA and flux soldering according to the microstructural study results before and thermal aging. This paper verifies that the FA atmosphere is suitable for various lead-free solders and substrates to achieve fluxless soldering and then provides a theoretical reference for the industrialization of formic acid atmosphere in electronic packaging.http://www.sciencedirect.com/science/article/pii/S2666330922000243SolderingWettabilityInterfacial reactionFluxlessFormic acid
spellingShingle Siliang He
Yuhao Bi
Yu-An Shen
Zhikuan Chen
Gao Yue
Chuan Hu
Hiroshi Nishikawa
Contact angle analysis and intermetallic compounds formation between solders and substrates under formic acid atmosphere
Journal of Advanced Joining Processes
Soldering
Wettability
Interfacial reaction
Fluxless
Formic acid
title Contact angle analysis and intermetallic compounds formation between solders and substrates under formic acid atmosphere
title_full Contact angle analysis and intermetallic compounds formation between solders and substrates under formic acid atmosphere
title_fullStr Contact angle analysis and intermetallic compounds formation between solders and substrates under formic acid atmosphere
title_full_unstemmed Contact angle analysis and intermetallic compounds formation between solders and substrates under formic acid atmosphere
title_short Contact angle analysis and intermetallic compounds formation between solders and substrates under formic acid atmosphere
title_sort contact angle analysis and intermetallic compounds formation between solders and substrates under formic acid atmosphere
topic Soldering
Wettability
Interfacial reaction
Fluxless
Formic acid
url http://www.sciencedirect.com/science/article/pii/S2666330922000243
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